analytical chem

How to Interpret the Results
The sample is identified by comparing the observed flame color against known values from a table or chart.
Red
Carmine to Magenta: Lithium compounds. Masked by barium or sodium.
Scarlet or Crimson: Strontium compounds. Masked by barium.
Red: Rubidium (unfiltered flame)
Yellow-Red: Calcium compounds. Masked by barium.
Yellow
Gold: Iron
Intense Yellow: Sodium compounds, even in trace amounts. A yellow flame is not indicative of sodium unless it persists and is not intensified by addition of 1% NaCl to the dry compound.
White
Bright White: Magnesium
White-Green: Zinc
Green
Emerald: Copper compounds, other than halides. Thallium.
Bright Green: Boron
Blue-Green: Phosphates, when moistened with H₂SO₄ or B₂O₃.
Faint Green: Antimony and NH₄ compounds.
Yellow-Green: Barium, manganese(II), molybdenum.
Blue
Azure: Lead, selenium, bismuth, cesium, copper(I), CuCl₂ and other copper compounds moistened with hydrochloric acid, indium, lead.
Light Blue: Arsenic and come of its compounds.
Greenish Blue: CuBr₂, antimony
Purple
Violet: Potassium compounds other than borates, phosphates, and silicates. Masked by sodium or lithium.
Lilac to Purple-Red: Potassium, rubidium, and/or cesium in the presence of sodium when viewed through a blue glass.
Limitations of the Flame Test

• The test cannot detect low concentrations of most ions.
• The brightness of the signal varies from one sample to another. For example, the yellow emission from sodium is much brighter than the red emission from the same amount of lithium.
• Impurities or contaminants affect the test results. Sodium, in particular, is present in most compounds and will color the flame. Sometimes a blue glass is used to filter out the yellow of sodium.
• The test cannot differentiate between all elements. Several metals produce the same flame color. Some compounds do not change the color of the flame at all.

Primary Reference: Lange's Handbook of Chemistry, 8th Edition, Handbook Publishers Inc., 1952.

Flame Test Colors

Symbol	Element	Color
As	Arsenic	Blue
B	Boron	Bright green
Ba	Barium	Pale/Yellowish Green
Ca	Calcium	Orange to red
Cs	Cesium	Blue
Cu(I	Copper(I)	Blue
Cu(II)	Copper(II) non-halide	Green
Cu(II)	Copper(II) halide	Blue-green
Fe	Iron	Gold
In	Indium	Blue
K	Potassium	Lilac to red
Li	Lithium	Magenta to carmine
Mg	Magnesium	Bright white
Mn(II)	Manganese(II)	Yellowish green
Mo	Molybdenum	Yellowish green
Na	Sodium	Intense yellow
P	Phosphorus	Pale bluish green
Pb	Lead	Blue
Rb	Rubidium	Red to purple-red
Sb	Antimony	Pale green
Se	Selenium	Azure blue
Sr	Strontium	Crimson
Te	Tellurium	Pale green
Tl	Thallium	Pure green
Zn	Zinc	Bluish green to whitish green